18. Power of the State Government to modify the Schedules.

Schedule 1
[ See Rules 2(a)(i), 3(1), 4(1)(a) and 4(2)(1)]
Indicative Criteria and List of Chemicals
Indicative Criteria and List of Chemicals
Part I
Indicative Criteria
(a) Toxic Chemicals: Chemicals having the following values of acute toxicity and which, owing to their physical and chemical properties are capable of producing major accident hazards.
Sl. No.
Degree of Toxicity
LD 50 absorbed orally in rate mg./kg. body weight
LD 50 by continues absorption in rate or rabbits
mg./Kg. body weight
LC 50 absorbed by inhalation (4 hours) in rates
mg./litre
1.
Extremely toxic
< = 50
< = 200
0.1-0.5
2.
Highly toxic
51-500
201-2090
0.5-2.0
(b) Highly Flammable Chemicals :
(i) Flammable gases : Chemicals which in the gaseous state at normal pressure and mixed with air become flammable and the boiling point of which at normal pressure is 20 degrees C or below;
(ii) Highly flammable liquids : Chemicals which have a flash point lower than 23 degrees C and the boiling point of which at normal pressure is above 20 degrees C;
(iii) Flammable liquids : Chemicals which have a flash point lower than 65 degrees C and which remain liquid under pressure, where particular processing conditions, such as high pressure and high temperature may create major accident hazards.
(c) Explosives : Chemicals which may explode under the effect of flames, heat or photo chemical condition, or which are more sensitive to shocks or friction than dinitrobenzene.
Part II
List of Hazardous Chemicals
Sl.No.
Name of the Chemical
(1)
(2)
1.
Acetone
2.
Acetone Cyanohydrine
3.
Acetyl Chloride
4.
Acetylene (Ethyne)
5.
Acrolein (2-Propenal)
6.
Acrylonitrile
7.
Aldicarb
8.
Aldrine
9.
Alkyl Phthalate
10.
Allyl Alcohol
11.
Allylamine
12.
Alpha Naphthl Thiourea (Antu)
13.
4-A minodiphenyl
14.
2-Aminophenol
15.
Amiton
16.
Ammonia
17.
Ammonium Nitrate
18.
Ammonium Nitrate in fertilizers
19.
Ammonium Sulfamate
20.
Anabasine
21.
Aniline
22.
P-Anisidine
23.
Antimony & Compounds
24.
Antimony Hydride (Stibine)
25.
Arsenic Hydride (Arsine)
26.
Arsenic Pentoxide, Arsenic (V) Acids & Salts
27.
Arsenic Trioxide, Arsenious (III) Acids & Salts
28.
Asbetos
29.
Azinphos-Ethyl
30.
Azinphos-Methyl
31.
Barium Azide
32.
Benzene
33.
Benzidine
34.
Benzidine Salts
35.
Benzoquinone
36.
Benzoyl Chloride
37.
Benzoyl Peroxide
38.
Benzyl Chloride
39.
Benzyl Cyanide
40.
Beryllium (Powders, Compounds)
41.
Biphenyl
42.
Bis (2-Chloromethyl) Ketone
43.
Bis (2, 4, 6-Trinitrophenyl) Amine
44.
Bis (2-Chloroethyl) Sulphide
45.
Bis (Chloromethyl) Ether
46.
2, 2-Bis (tert-Butylperoxy) Butane
47.
1, 1-Bis (tert-Butylperoxy) Cyclohexane
48.
Bis-1, 2 (Tribromophenoxy)-Ethane
49.
Bisphenol
50.
Boron & Compounds
51.
Bromine
52.
Bromine Pentafluoride
53.
Bromoform
54.
1.3-Butadiene
55.
Butane
56.
N-Butanethiol
57.
2-Butanone
58.
Butoxy Ethanol
59.
Butyl Glycidal Ether
60.
tert-Butyl Peroxyacetate
61.
tert-Butyl Peroxyisobutyrate
62.
tert-Butyl Peroxyisopropyl Carbonate
63.
tert-Butyl Peroxymaleate
64.
tert-Butyl Peroxypivalate
65.
Butyl Vinyl Ether
66.
Butylamine
67.
C9-Aromatic Hydrocarbon Froction
68.
Cadmium & Compounds
69.
Cadmium Oxide (Fumes)
70.
Calcium Cyanide
71.
Cap tan
72.
Captofol
73.
Carbaryl(Sevin)
74.
Cabofuran
75.
Carbon Disulphide
76.
Carbon Monoxide
77.
Carbon Tetrachloride
78.
Carbophenothion
79.
Cellulose Nitrate
80.
Chlorates (use in explosives)
81.
Chlordane
82.
Chlorfenvinphos
83.
Chlorinated Benzenes
84.
Chlorine
85.
Chlorine Dioxide
86.
Chlorine Oxide
87.
Chlorine Trifluoride
88.
Chlormequate Chloride
89.
Chloroacetal Chloride
90.
Chloroacetaldehyde
91.
2-Chloroaniline
92.
4-Chloroaniline
93.
Chlorobenzene
94.
Chorodiphenyl
95.
Chloroepoxypropane
96.
Chloroethanol
97.
Chloroethyl Chloroformate
98.
Chlorofluorocarbons
99.
Chloroform
100.
4-(Chloroformyl), Morpholine
101.
Chloromethane
102.
Chloromethyl Ether
103.
Chloronitrobenzene
104.
Chloroprene
105.
Chlorosulphonic Acid
106.
Chlorotrini trobenzene
107.
Chloroxuron
108.
Chromium & Compounds
109.
Cobolt & Compounds
110.
Copper & Compounds
111.
Coumafuryl
112.
Coumaphos
113.
Coumatetralyl
114.
Cresols
115.
Crimidine
116.
Cumene
117.
Cyanophos
118.
Cyanothoate
119.
Cyanuric Fluoride
120.
Cyclohexane
121.
Cyclohexanol
122.
Cyclohexanone
123.
Cyclohexamide
124.
Cyclopentadiene
125.
Cyclopentane
126.
Cyclotetramethylenetetranitramine
127.
Cyclotrimethylenetrinitramine
128.
DDT
129.
Decabromodiphenyl Oxide
130.
Demeton
131.
DI-Isobutyryl Peroxide
132.
DI-n-Propyl Peroxydicarbonate
133.
DI-sec-Butyl Peroxydicarbonate
134.
Dialifos
135.
Diazodini trophenol
136.
Diazomethane
137.
Dibenzyl Peroxydicarbonate
138.
Dichloroacetylene
139.
o-Dichlorobenzene
140.
p-Dichlorobenzene
141.
Dichloroethane
142.
Dichloroethyl Ether
143.
2, 4-Dicolorophenol
144.
2, 6-Dichlorophenol
145.
3, 4-Dichlorophenoxy Acetic Acid (2, 4-D)
146.
1, 2-Dichloropropane
147.
3, 5-Dichlorosalicylic Acid
148.
Dichlorovos (DDVP)
149.
Dicrotophos
150.
Dieldrin
151.
Diepoxybutane
152.
Diethyl Peroxydicarbonate
153.
Diethylene Glycol Dinitrate
154.
Diethylene Triamine
155.
Diethyleneglycol Butyl Ether/Diethyleneglycol Butyl Acetate
156.
Diethylenetriamine (Deta)
157.
Diglycidyl Ether
158.
2, 2-Dihydroperoxypropane
159.
Diisobutyryl Peroxide
160.
Dimefox
161.
Dimethoate
162.
Dimethyl Phosphoramidocyandic Acid
163.
Dimethyl Phthalate
164.
Dimethylcarbomoyl Chloride
165.
Dimethylnitrosamine
166.
Dinitrophenol Salts
167.
Dinitrotoluene
168.
Dinitro-o-Cresol
169.
Dioxane
170.
Dioxathion
171.
Dioxolane
172.
Diphacinone
173.
Diphosphoramide Octamethyl
174.
Dipropylene Glycolmethylether
175.
Disulfoton
176.
Endosulfan
177.
Endrin
178.
Epichlorohydrine
179.
Epn
180.
1, 2-Epoxypropane
181.
Ethion
182.
Ethyl Carbamate
183.
Ethyl Ether
184.
2-Ethyl Hexanol
185.
Ethyl Mercaptan
186.
Ethyl Methacrylate
187.
Ethyl Nitrate
188.
Ethylamine
189.
Ethylene
190.
Ethylene Chlorohydrine
191.
Ethylene Diamine
192.
Ethylene Dibromide
193.
Ethylene Dichloride
194.
Ethylene Glycol Dinitrate
195.
Ethylene Oxide
196.
Ethylene Imine
197.
Ethylthiocyanate
198.
Fensulphothion
199.
Fluenetil
200.
4-Fluoro, 2-Flydroxybutyric Acid & Salts, Esters, Amides
201.
Fluoroacetic Acid & Salts, Esters, Amides
202.
4-Fluorobutyric Acid & Salts, Esters, Amides
203.
4-Fluorochrotonic Acid & Salts, Esters, Amides
204.
Formaldehyde
205.
Glyconitrile (Hydroxyacetonitrile)
206.
1 -Guanyl-4-Nitrosaminoguanyl-1-Tetrazene
207.
Heptachlor
208.
Hexachloro Cyclopentadiene
209.
Hexachlorocyclohexane
210.
Hexachlorocyclomethane
211.
1, 23, 7, 8, 9-Hexachlorodibenzo-p-Dioxine
212.
Hexafluopropene
213.
Hexamethylphosphoramide
214.
3,3,6,6,9,9-Hexamethyl-1,2,4,5,-Tetroxacyclononane
215.
Hexamcthylenediamine
216.
Hexane
217.
2,2',4,4'6,6'-Flexanitrostilbene
218.
Hexavalent Chromium
219.
Hydrazine
220.
Hydrizine Nitrate
221.
Hydrochloric Acid
222.
Hydrogen
223.
Hydrogen Bromide (Hydrobromic Acid)
224.
Hydrogen Chloride (Liquefied Gas)
225.
Hydrogen Cyanide
226.
Hydrogen Fluoride
227.
Hydrogen Selenide
228.
Hydrogen Sulphide
229.
Hydroquinone
230.
Iodine
231.
Isobenzan
232.
Isodrin
233.
Isophorone Diisocyanate
234.
Isopropyl Ether
235.
Juglone (5-Hydroxynaphthalene-1,4-Dione)
236.
Lead (inorganic fumes & dusts)
237.
Lead 2,4,6-Trinitroresorcinoxide (Lead Styphnate)
238.
Lead Azide
239.
Letophos
240.
Lindane
241.
Liquefied Petroleum Gas (LPG)
242.
Maleic Anhydride
243.
Manganese & Compounds
244.
Mercapto Benzothiazole
245.
Mercury Alkyl
246.
Mercury Fulminate
247.
Mercury Methyl
248.
Methacrylic Anhydride
249.
Methacrylonitrile
250.
Methacryloyl Chloride
251.
Methamidophos
252.
Methanesuphonyl Fluoride
253.
Methanethiol
254.
Methoxy Ethanol (2-Methyl Cellosolve)
255.
Methoxyethylmercuric Acetate
256.
Methyl Acrylate
257.
Methyl Alcohol
258.
Methyl Amylketone
259.
Methyl Bromide (Bromomethane)
260.
Methyl Chloride
261.
Methyl Chloroform
262.
Methyl Cyclohexene
263.
Methyl Ethyl Ketone Peroxide
264.
Methyl Hydrazine
265.
Methyl Isobutyl Ketone Peroxide
266.
Methyl Isobutyl Ketone Peroxide
267.
Methyl Isocyanate
268.
Methyl Isothiocyanate
269.
Methyl Mercaptan
270.
Methyl Methacrylate
271.
Methyl Parathion
272.
Methyl Phosphonic Dichloride
273.
N-Methyl, 2,4,6-Tetranitroaniline
274.
Methylene Chloride
275.
4/4-Methylenebis (2-Chloroaniline)
276.
Methyltrichlorosilane
277.
Mevinphos
278.
Molybdenum & Compounds
279.
N-Methyl-N,2,4,6-N-Tetranitroaniline
280.
Naphtha (Coal Tar)
281.
2-Naphthylamine
282.
Nickel & Compounds
283.
Nickel Tetracarbonyl
284.
O-Nitroaniline
285.
P-Nitroaniline
286.
Nitrobenzene
287.
P-Nitrochlorobenzene
288.
Nitrocyclohexane
289.
Nitroethane
290.
Nitrogen Dioxide
291.
Nitrogen Oxides
292.
Nitrogen Trifluoride
293.
Nitroglycerine
294.
P-Nitrophenol
295.
1-Nitropropane
296.
2-Nitropropane
297.
Nitrosodimethylamine
298.
Nitrotolune
299.
Octabromophenyl Oxide
300.
Oleum
301.
Oleylamine
302.
OO-Diethyl S-Ethylsulphinylmethyl Phosphorothioate
303.
OO-Diethyl S-Ethylsulphonylmethyl Phosphorothioate
304.
OO-Diethyl S-Ethylthiomethyl Phosphorothioate
305.
OO-Diethyl S-Isopropyl thiomethyl Phosphorodithioate
306.
OO-Diethyl S-Propylthiomethyl Phosphorodithioate
307.
Oxyamyl
308.
Oxydisulfoton
309.
Oxygen (Liquid)
310.
Oxygen Difluoride
311.
Ozone
312.
Paraoxon (Diethyl 4-Nitrophenyl Phosphate)
313.
Paraquat
314.
Parothion
315.
Parathion Methyl
316.
Paris Green (Bis Aceto Hexametaarsenitoteracopper)
317.
Pentaborane
318.
Pentabromodiphenyl Oxide
319.
Pentabromophenol
320.
Pentachloro Naphthalene
321.
Pen tachloroethane
322.
Pentachlorophenol
323.
Pentaerythritol Tetranitrate
324.
Pentane
325.
Peracetic Acid
326.
Perchloroethylene
327.
Perchloromethyl Mercaptan
328.
2-Pentanone, 4-Methyl
329.
Phenol
330.
Phenyl Glycidal Ether
331.
Phenylene P-Diamine
332.
Phenylmercury Acetate
333.
Phorate
334.
Phosacetim
335.
Phosalane
336.
Phosfolan
337.
Phosgene (Carbonyl Chloride)
338.
Phosmet
339.
Phosphamidon
340.
Phosphine (Hydrogen Phoshii E)
341.
Phosphoric Acid and Esters
342.
Phosphoric Acid Bromoethyl Bromo (2, 2-Dimethyl-propyl)
Bromoethyl Ester
343.
Phosphoric Acid Bromoethyl Bromo (2, 2-Dimethyl-propyl)
Chloroethyl Ester
344.
Phosphoric Acid, Chloroethyl Bromo (2, 2-Dimethoxyl-propyl)
Chloi Oethyl Ester
345.
Phosphorus & Compounds
346.
Phostalan
347.
Picric Acid (2, 4, 6-Trinitrophenol)
348.
Polybrominated Biphenyls
349.
Potassium Arsenite
350.
Potassium Chlorate
351.
Promurit (1-(3,4-Dichlorophenyl)-2-Triazene Thiocarboxamide)
352.
1,3-Propanesultone
353.
1-Propen,-2-Chloro-1,3-Diol-Diacetate
354.
Propylene Dichloride
355.
Propylene Oxide
356.
Propyleneimine
357.
Pyrazoxon
358.
Selenium Hexafluoride
359.
Semicarbazide Hydrochloride
360.
Sodium Arsenite
361.
Sodium Azide
362.
Sodium Chbrate
363.
Sodium Cyanide
364.
Sodium Picramate
365.
Sodium Selenite
366.
Styrene, 1,1,2,2-Tetrachloroethane
367.
Sulfotep
368.
Sulphur Dichloride
369.
Sulphur Dioxide
370.
Sulphur Trioxide
371.
Sulphuric Acid
372.
Sulphoxide, 3-Chloropropyloctyl
373.
Tellurium
374.
Tellurium Hexafluoride
375.
Tepp
376.
Terbufos
377.
alpha-Terabromobisphenol
378.
2 2 5 6-Tetrachloro-2, 5-Cyclohexadiene-y, 4-Dione
379.
2 3 7 8-Tetrachlorodibenzo-li-Dioxin (TCDD)
380.
Tetraethyl Lead
381.
Tetrafluoroethane
382.
Tetramethylenedisulphotetramine
383.
Tetranitromethane
384.
Tetranitromethane
385.
Thallium & Compounds
386.
Thionazin
387.
Thionyl Chloride
388.
Tirpate
389.
Toluene
390.
Toluene-2-4-Diisocyanate
391.
o-Toluidine
392.
Toluene 2,6-Diisocyanate
393.
T rans-1,4 Chlorobutene
394.
1-Tri.(Cyclohexyl) Stannyl-1H-1,2,4-Triazole
395.
1 3 5-Triamino-2,4,6-Trinitrobenzene
396.
2 4 6-Tribromophenol
397.
Trichloro Acetyl Chloride
398.
Trichloro Ethane
399.
Trichloro Naphthalene
400.
Trichlorochloromethylsilane
401.
Trichlorodichlorophenylsilane
402.
1, 1,1-Trichloroethane
403.
Trichloroehthyllane
404.
Trichloroethylene
405.
Trichloromethanesulphenyl Chloride
406.
2,2,6-Trichlorophenol
407.
2,4,5-Trichlorophenol
408.
Triethylamine
409.
Triethylenemelamine
410.
Trimethyl Chlorosilane
411.
Trimethylolpropane Phosphite
412.
Trinitroaniline
413.
2,4,6-T rinitroanisole
414.
Trinitrobenzene
415.
Trinitrobenzoic Acid
416.
Trinitrocresol
417.
2,4,6-Trinitrophenetole
418.
2,4,6-Trinitroresorcinol (Styphnic Acid)
419.
Trinitrotoluene
420.
Triopthocresyl Phosphate
421.
Triphenyltin Chloride
422.
Terpentine
423.
Uranium & Compounds
424.
Vanadium & Compounds
425.
Vinyl Chloride
426.
Vinyl Fluoride
427.
Vinyl Toluene
428.
Warfarin
429.
Xylene
430.
Xylidine
431.
Zine & Compounds
432.
Zirconum & Compounds
Schedule 2
[ See Rules 2(a)(ii), 4(1)(b), 4(2)(1) and 6(1)(c) and (d)]
Isolated storage of Installation other than those covered by Schedule 4
Isolated storage of Installation other than those covered by Schedule 4
(a) The quantities is out below relate to each installation or group of installations belonging to the occupier where the distance between installations is not sufficient to avoid in foreseeable circumstances any aggravation of major accident hazards. These quantities apply in any case to each of the installations belonging to the same occupier where the distance between the installations is less than 500 metres.
(b) For the purpose of determining the quantity of a hazardous chemical at an isolated storage account shall also be taken of any hazardous chemical which is-
(i) in that part of any pipeline under the control of the occupier having control of the site, which is within 500 metres of that site and connected to it;
(ii) at any other site under the control of the occupier any part of the boundary of which is 500 metres of the said site; and
(iii) in any vehicle, vessel, aircraft or hovercraft under the control of the same occupier which is used for storage purpose, either at the site or within 500 metres of it;
Sl. No.
Chemical or groups of chemicals
Quantity (tonnes)
For application of Rules 4, 5 and 7 to 9
For application of Rules 10 to 15
(Col. 1)
(Col. 2)
(Col. 3)
(Col. 4)
1.
Acrynitrite
350
5000
2.
Ammonia
60
600
3.
Ammonium nitrate (a)
350*
2500*
4.
Ammonium nitrate fertilizers (b)
1250
10000
5.
Chloride
10
25
6.
Flammable gases as defined in Schedule 1, paragraph (b) (i)
50
300
7.
Highly flammable liquid as defined in Schedule 1, paragraph
(b) (ii)
10000
100000
8.
Liquid Oxygen
200
2000
9.
Sodium Chlorate
25
250
10.
Sulphur dioxide
20
500
11.
Sulphur trioxide
15
100
* Where this chemical is in a state which gives it properties capable of creating a major accident hazard.
Foot Notes : (a) This applies to ammonium nitrate and mixtures of ammonium nitrate where the nitrogen content derived from the ammonium nitrate is greater than 2 per cent by weight and to aqueous solutions of ammonium nitrate where the concentration of ammonium nitrate is greater than 90 per cent by weight.
(b) This applies to straight ammonium nitrate fertilisers and to compound fertilisers where the nitrogen content derived from the ammonium nitrate is greater than 28 per cent by weight (a compound fertiliser contains ammonium nitrate together with phosphate and/or potash).
Schedule 3
[ See Rules 2(a)(iii), 5 and 6(1)(a) and (b)]
List of hazardous chemicals for application of Rules 5 and 7 to 15
List of hazardous chemicals for application of Rules 5 and 7 to 15
(a) The quantities set out below relate to each installation or group of installations belonging to the same occupier where the distance between the installations is not sufficient to avoid in foreseeable circumstances, any aggravation of major accident hazards. These quantities apply in any case to each group of installations belonging to the same occupier where the distance between the installations is less than 500 metres.
(b) For the purpose of determining the quantity of hazardous chemical in an industrial installation, account shall also be taken of any hazardous chemical which is-
(i) in that part of any pipeline under the control of the occupier having control of the site, which is within 500 metres of that site and connected to it;
(ii) at any other site under the control of the same occupier any part of the boundary of which is within 500 metres of the said site; and
(iii) in any vehicle, vessel, aircraft or hovercraft under the control of the same occupier which is used for storage purpose either at the site or within 500 metres of it.
Part I
Named Chemicals
Sl. No.
Chemicals
Quantity
CAS No.
For application of Rules 5, 7 to 9 and 13 to 15
For application of Rules 10 to 12
(1)
(2)
(3)
(4)
(5)
Group 1-Toxic Chemicals :
1.
Aldicarb
100 Kg
…...
116-06-3
2.
4-Aminodiphenyl
1 Kg
…...
92-67-1
3.
Amiton
1 Kg
…...
78-53-5
4.
Anabasine
100 Kg
…...
494-52-0
5.
Arsenic pentoxide, Arsenic (v) Acid & Salts
500 Kg
…...
6.
Asenic Trioxide, Arsenious (III) acid & Salts
100 Kg
…...
7.
Arrsne :(Arsenic hydride)
10 Kg
…...
7784-42-1
8.
Aziniphos-ethyl
100 Kg
…...
2642-71-9
9.
Aziniphos-methyl
100 Kg
…...
86-50-0
10.
Benzidine
1 Kg
…...
92-87-5
11.
Benzidine salts
1 Kg
…...
12.
Becoryllium (powders, compounds)
10 Kg
…...
13.
Bis (2 chloroethyl) sulphide
1 Kg
…...
505-60-2
14.
Bis (chloromethyl) ether
1 Kg
…...
542-88-1
15.
Carboturan
100 Kg
…...
1563-66-2
16.
Carbophenothion
100 Kg
…...
786-19-6
17.
Chlorfenvinphos
100 Kg
…...
470-90-6
18.
4-(Chloroformyl) morpholine
1 Kg
…...
15159-40-7
19.
Chloromethyl methyl ether
1 Kg
…...
107-30-2
20.
Cobalt metal, Oxides, Carbonates, Sulphides, as powders
1 kg
…...
21.
Crimidine
100 Kg
…...
535-89-7
22.
Cyanthoate
100 Kg
…...
3734-95-0
23.
Cycloheximide
100 Kg
…...
66-81-9
24.
Demeton
100 Kg
…...
8065-48-3
25.
Dralifos
100 Kg
…...
10311-84-9
26.
oo-Diethyl, S-ethylsulphinyl methyl phosphorthioate
100 Kg
…...
2588-05-8
27.
oo-Diethyl S-ethylsulphonyl methyl phosphorthioate
100 Kg
…...
2588-06-9
28.
oo-Diethyl S-ethylthiomethyl phosphordithioates
100 Kg
…...
2600-69-3
29.
oo-Diethyl S-isoprophlthymethyl phosphorodithioate
100 Kg
…...
78-52-4
30.
oo-Diethyl S-propylthiomethyl phosphorothioate
100 Kg
…...
3309-68-0
31.
Dimefox
100 Kg
…...
115-26-4
32.
Dimethylcarbamoyl chloride
1 Kg
…...
79-44-7
33.
Dimethylnitrosamine 1 K, 62-75-9
…...
34.
Dimethyl phosphoramidocyanidic acid
1 t
…...
63917-41-9
35.
Diphacinone
100 Kg
…...
82-66-6
36.
Disulfoton
100 Kg
…...
298-04-4
37.
EPN
100 Kg
…...
2104-64-5
38.
Ethion
100 Kg
…...
563-12-2
39.
Fensulfothion
100 Kg
…...
115-90-2
40.
Fluenetil
100 Kg
…...
4301-50-2
41.
Fluoroacetic acid
1 Kg
…...
144-49-0
42.
Fluoroacetic acid, salts
1 Kg
…...
43.
Fluoroacetic acid, esters
1 Kg
…...
44.
Fluoroacetic acid, amides
1 Kg
…...
45.
4-Fluorobutyric acid
1 Kg
…...
462-23-7
46.
4-Fluorobutyric, acid, salts
1 Kg
…...
47.
4-Fluorobutyric, esters
1 Kg
…...
48.
4-Fluorobutyric acid, amides
1 Kg
…...
49.
4-Fluorocronotic acid
1 Kg
…...
37759-72-1
50.
4-Fluorocronotic acid, salts
1 Kg
…...
51.
4-Fluorocronotic acid, esters
1 Kg
…...
52.
4-Fluorocronotic acid amides
1 Kg
…...
53.
4-Fluoro-2-hydroxybutyric acid
1 Kg
…...
54.
4-Fluoro-hydroxybutyric acid, salts
1 Kg
…...
55.
4-Fluoro-2-hydroxybutyric acid esters
1 Kg
…...
56.
4-Fluoro-2-hydroxybutyric acid, amides
1 Kg
…...
57.
Glycolonitrite (hydroxyacetonitrite)
100 Kg
…...
107-16-1
58.
1, 2, 3, 7, 8, 9 Hexachlorodibenzo-p-dioxin
100 Kg
…...
19408-74-3
59.
Hexamethylphosphoramide
1 Kg
…...
680-31-9
60.
Hydrogen selenide
10 Kg
…...
7783-07-5
61.
Isobenzan
100 Kg
…...
297-78-9
62.
Isodrin
100 Kg
…...
465-73-6
63.
Jugione (5-Hydroxynaphthalene-1 ,-dione
100 Kg
…...
481-39-0
64.
4,4’-Methylenebi (2-chloroanniline)
10 Kg
…...
101-14-4
65.
Methyl isocyanate
150 Kg
150 Kg
624-83-9
66.
Mevinphos
100 Kg
…...
7786-34-7
67.
2-Napathylamine
1 Kg
…...
91-59-8
68.
Nickel metal, oxides, carbonates sulphide, as powders
1 t
…...
69.
Nickel tetracarbonyl
10 Kg
…...
13463-39-3
70.
Oxydisulfoton
100 Kg
…...
24970-7-6
71.
Oxygen difluoride
10 Kg
…...
7783-41-7
72.
Paraoxon (diethyl 4-nitrophenyl phosphate
100 Kg
…...
311-45-5
73.
Parathion
100 Kg
…...
56-38-2
74.
Parathion-methyl
10 Kg
…...
98-00-0
75.
Pentaborane
100 Kg
…...
19624-22-7
76.
Phorate
100 Kg
…...
298-02-2
77.
Phasacetim
100 Kg
…...
4104-14-7
78.
Phosgene (carbonyl chloride)
750 Kg
750 Kg
75-44-5
79.
Phosphamidon
100 Kg
…...
13171-21-6
80.
Phospaine (Hydrogen Phosphide)
100 Kg
…...
7803-51-2
81.
Promurit (1-(3,4-Dichiorophenyl) 1-3-triazenethio carboxamide
100 Kg
…...
5836-73-7
82.
1.3-Propanesultoge
1 Kg
…...
1120-71-4
83.
1-Prope-2-chloro-1 3-diol diacetate
10 Kg
…...
0118-72-6
84.
Pyrazoxon
100 Kg
…...
108-34-9
85.
Selenium hexafluoride
100 Kg
…...
7783-79-1
86.
Sodium selenite
100 Kg
…...
10102-18-8
87.
Stibine (Antimony hydride)
100 Kg
…...
7803-52-3
88.
Sulfotop
100 Kg
…...
3689-24-5
89.
Sulphur dichloride
1 t
…...
10545-99-0
90.
Tellurium hexafluoride
100 Kg
…...
7783-80-4
91.
TEPP
100 Kg
…...
107-49-3
92.
2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD)
1 Kg
…...
1746-01-6
93.
Tetramethylenedisulphotetramine
1 Kg
…...
0-12-6
94.
Thionazin
100 Kg
…...
297-97-2
95.
Tirpate (2 4-Dimethyl-1 3-dithiolane 2-carboxaldehyde 0-
methyl-carbomoyloxime)
100 Kg
…...
26419-73-8
96.
Trichloromethane sulphenyl chloride
100 Kg
…...
594-42-3
97.
l-Tri (cyclohexyl) stann 1-1 H-1.2.4-triazole
10 Kg
…...
41083-11-8
98.
Triethylenemelamine
13 Kg
…...
51-18-3
99.
Warfarin
100 Kg
…...
81-81-2
Group 2- Toxic Chemicals:(Quantity VI tonne)
100.
Acetone cyanohydrin (2-Cyariopropan 2-ol)
200 Kg
…...
75-86-5
101.
Acrolein (2-Propenal)
20 t
…...
107-02-8
102.
Acrylonitrite
20 t
200 t
107-18-1
103.
Allyl alcohol (2-Propen 1 -ol)
200 t
…...
107-18-6
104.
Allylamine
200 t
…...
107-11-9
105.
Ammonia
50 t
50 t
7666-41-7
106.
Bromine
40 t
…...
7726-95-0
107.
Carbon disulphide
20 t
200 t
75-15-9
108.
Chlorine
10 t
25 t
778-50-5
109.
Diphyenl Methane diisocyanate (MDI)
20 t
…...
101-68-8
110.
Ethylene dibromide 1,2-Dibromomethane)
5 t
…...
106-93-4
111.
Ethyleneimine
50 t
…...
151-56-4
112.
Formaldehide (concentration=90%)
5 t
…...
50-00-0
113.
Hydrogen chloride (liquefied gas)
25 t
250 t
7647-01-0
114.
Hydrogen cyanide
5 t
20 t
74-90-8
115.
Hydrogen fluoride
5 t
50 t
7664-39-3
116.
Hydrogen Sulphide
5 t
50 t
7783-06-4
117.
Methyl bromide (Bromomethane)
20 t
…...
74-83-9
118.
Nitrogen oxides
50 t
…...
11104-93-1
119.
Propyleneimine
50 t
…...
75-55-8
120.
Sulphur dioxide
10 t
250 t
7446-09-5
121.
Sulphur trioxide
15 t
75 t
7446-11-9
122.
Tetraethyl lead
5 t
…...
78-00-2
123.
Tetramethyl lead
5 t
…...
75-74-1
124.
Toluene diisocyanate (TDI)
10 t
…...
584-84-9
Group 3-Highly Reactive Chemicals:
125.
Acetylene (ethyne)
5 t
…...
74-86-2
126.
(a) Ammonium nitrate (1)
350 t
25.00 t
6484-52-2
(b) Ammonium nitrate in the form of fertiliser (2)
1,250 t
…...
127.
2.2-Bis (tert-butyl-peroxy) butane (concentration >=70%)
5 t
…...
2167-23-9
128.
1 -1 -Bis (tert-butyl)-peroxy) cyclohexane (concentration
>=80%)
5 t
…...
3006-86-8
129.
Tert-Butyl peroxyacetate (concentration >= 70%)
5 t
…...
107-71-1
130.
Tert-Butyl Peroxyisobutyrate (concentration >= 80%)
5 t
…...
109-13-7
131.
Tert-Butyl Peroxyisopropyl carbonate (concentration >= 80%)
5 t
…...
2372-21-6
132.
Tert-Butyl peroxymaleate (concentration >= 80%)
5 t
…...
1931-62-0
133.
Tert-Butyl Peroxypivalate (concentration >= 77%)
50 t
…...
927-07-1
134.
Dibenzyl peroxydicarbonate (concentration>=90%)
5 t
…...
2144-45-8
135.
Di-sec-butyl peroxydicarbonate (concentration>=80%)
5 t
…...
19910-5-7
136.
Diethyl peroxydicarbonate (concentration>=30 per cent)
50 t
…...
14666-78-5
137.
2.2-Dihydroperoxypropane (concentration>=30 per cent)
5 t
…...
2614-76-8
138.
Di-isobutryl peroxide (concentration>=50 per cent)
50 t
…...
3437-84-1
139.
Di-n-propyl peroxydicarbonate (concentration>=80%)
5 t
…...
16066-38-9
140.
Ethylene oxide
5 t
50 t
75-21-8
141.
Ethyl nitrate
50 t
625-58-1
142.
3, 3, 6, 6, 9, 9-Hexamethyl-1, 2, 4, 5-tetroxacyclonane
(concentration >=75 per cent)
50 t
…...
22397-33-7
143.
Hydrogen
2 t
50 t
1333-74-0
144.
Liquid oxygen
200 t
…...
7782-44-7
145.
Methyl ethyl Ketone peroxide (concentration >= 0%)
5 t
…...
133-23-4
146.
Methyl isobutyl ketone peroxide (concentration>=60%)
50 t
…...
37206-20-51
147.
Peracetic acid (concentration>=60%)
50 t
…...
79-21-0
148.
Propylene oxide
5 t
…...
75-56-9
149.
Sodium chlorate
25 t
…...
7775-09-9
Group 4-Explosive Chemicals :
150.
Barium azide
50 t
…...
18810-58-7
151.
Bis (2,4,6-trinite phenyl) amine
50 t
…...
131-73-7
152.
Chlorotrinitrobenzene
50 t
…...
28260-61-9
153.
Cellulose nitrate (containing=12.6% nitrogen)
50 t
…...
9004-70-0
154.
Cyclotetramethylene tetranitramine
50 t
…...
2891-41-0
155.
Cyclotrimethylenetrinitroamine
50 t
…...
121-82-4
156.
Diazodinitrophenol
10 t
…...
7008-81-3
157.
Diethylene glycol dinitrate
10 t
…...
693-21-0
158.
Dinitrophenol salt 50 t
…...
159.
Ethlyene glycol dinitrate
10 t
…...
628-96-6
160.
1-Guanyl-4-nitroamineoguany1-1-tetrazene
10 t
…...
109-27-3
161.
2.2’,4.4'6.6;Hexanitrostibene
50 t
…...
20062-22-0
162.
Hydernine nitrate
50 t
…...
13464-97-6
163.
Lead azide
50 t
…...
13424-46-9
164.
Lead styphnate (lead 2.4.6-trinitroresorcinoxide)
50 t
…...
15245-44-0
165.
Mercury fulminate
10 t
…...
628-86-4
166.
N-Methyl-N 2.4.6-tetranitroaniline
50 t
…...
479-45-8
167.
Nitroglycerine
10 t
10 t
55-63-0
168.
Pentaerythritol tetranitrare
50 t
…...
78-11-5
169.
Picric acid (2,4,6-Trinitrophenol)
50 t
…...
88-89-1
170.
Sodium picramate
50 t
…...
831-52-7
171.
Styphnic acid (2.4.6-Trinitroresorcinol)
50 t
…...
82-7-13
172.
1.3.5-Triamino-2.4.6-T rinitrobenzene
50 t
…...
3058-38-6
173.
Trinitronailine
50 t
…...
26952-42-1
174.
2. 4. 6-Trinitroanisole
50 t
…...
606-35-9
175.
Trinitrobenzene
50 t
…...
25377-31-6
176.
Trinitrobenzoic acid
50 t
…...
35860-50-5
177.
Trinitrocresol
50 t
…...
28905-71-7
178.
2-4.6-Trinitrophenetole
50 t
…...
4732-14-3
179.
2.4.6-Trinitrotoluene
50 t
50 t
188-96-7
Part II
Classes of Chemicals not specifically named in Part I
Sl. No.
Classes of Chemicals
Quantity
CAS No.
For application of Rules 5, 7 to 9 and 13 to 15
For application of Rules 10 to 12
(1)
(2)
(3)
(4)
Group 5-Flammable Chemicals :
1.
Flammable gases :- Chemicals which in gaseous state
not normal pressure and mixed with air become flammable and the
boiling point of which at normal pressure is 20 degree C or below
15 t
200 t
2.
Highly flammable liquids :- Chemicals which have a
flash point lower than 23 degree C and the boiling point of which
at normal pressure is above 20 degree C
1000 t
50,000 t
3.
Flammable liquids :- Chemicals which have a flash
point lower than 65 degree C and which remain liquid under
pressure, where particular processing conditions, such as high
pressure and high temperature, may create major accident hazards
25 t
200 t
Footnotes. - (1) This applies to ammonium nitrate and mixtures of ammonium nitrate where the nitrogen content derived from the ammonium nitrate is greater than 28 per cent by weight and aqueous solutions of ammonium nitrate where the concentration of ammonium nitrate is greater than 90 per cent by weight.
(2) This applies to straight ammonium fertilisers and to compound fertilisers where the nitrogen content derived from the ammonium nitrate is greater than 28 per cent by weight (a compound fertiliser contains ammonium nitrate together with phosphate and/or potash).
*CAS Number (Chemical Abstracts Service Number means the number assigned to the Chemical assigned to the Chemical by the Chemical Abstract Service.
Schedule 4
[ See Rule 2(b)(i)]
Industrial installation within the meaning of Rule 2(b)(i)
Industrial installation within the meaning of Rule 2(b)(i)
(a) alkylation.
(b) animation by amonolysis.
(c) carbonylation.
(d) condensation.
(e) dehydrogenation.
(f) estefication.
(g) halogenation & manufacture of halogens.
(h) hydrogenation.
(i) hydrolysis.
(j) oxidation.
(k) polymerisation.
(l) sulphonation.
(m) desulphurization and manufacture and transformation of sulphur containing compounds.
(n) nitration and manufacture of nitrogen-containing compounds.
(o) manufacture of phosphorous-containing compounds.
(p) formulation of pesticides and of pharmaceutical products.
(q) distillation.
(r) extraction.
(s) salvation.
(t) mixing.
Schedule 5
[ See Rule 3 (2) and (3)]
Safety Data Sheet
Safety Data Sheet